Technology & Engineering

Proven anaerobic digestion, Pressurized Water Scrubbing, and high-pressure compression — nothing exotic, everything bankable.

Stage 1 — Anaerobic Digestion

Two of the 18 concrete cylindrical tanks (6 m diameter × 1 m deep) are being sealed and fitted with gas-collection infrastructure to operate as pilot anaerobic biodigesters. At commercial scale, purpose-built CSTR digesters of 100–200 m³ each are deployed.

Why Azolla is an Ideal Digester Substrate

High moisture content (~90%), soft cellular structure (no lignin to resist biological breakdown), and a favourable carbon-to-nitrogen ratio of approximately 10:1 — within the productive methanogenic range. The symbiotic Anabaena azollae cyanobacterium provides a nitrogen-rich substrate that supports robust microbial activity.

Raw Biogas Composition

ComponentConcentrationNote
CH₄ (methane)~50% volCombustible fraction
CO₂ (carbon dioxide)~50% volRemoved downstream by PWS
H₂S (hydrogen sulfide)200–2,000 ppmNatural variation; partially retained as odorant
N₂, H₂O vaporTraceMinimal impact on downstream process

Biodigester Design Parameters

ParameterPilot ValueCommercial Scale
Number of digester tanks22–4 × 100–200 m³ CSTR
Tank dimensions (each)6 m Ø × 1 m deepEngineered steel or RC vessels
Volume per tank~28.3 m³100–200 m³
Total active digester volume~56.6 m³200–800 m³
Operating temperatureAmbient (~28–34°C, mesophilic)Mesophilic (30–38°C)
Hydraulic retention time25–30 days20–30 days
Organic loading rate1.5–2.0 kg VS/m³/day2.0–3.0 kg VS/m³/day
CH₄ yield (azolla)~220–280 L CH₄/kg VS250 L/kg VS (base case)
Estimated biogas output~40–80 Nm³/day~400–800 Nm³/day
Gas collectionHDPE ring manifold + dome sealGas holder + compressor suction
Digestate useLiquid N-rich organic fertilizerSolid/liquid separation → bagged + tanker

⚠️ Conservative Biology Assumption

The v3.5R financial model uses 250 L CH₄/kg VS as the base-case methane yield — the mid-range of peer-reviewed azolla digestion literature (220–280 L/kg VS). The upper bound of 280 L/kg VS is treated as an unmodelled upside. This conservatism absorbs feedstock variability, seasonal temperature effects, and digester start-up lag.

Stage 2 — Pressurized Water Scrubbing (PWS)

PWS exploits a simple physical fact: at 8 bar(g) pressure, CO₂ is approximately 26 times more soluble in water than methane. Pressurize raw biogas, wash it with cold water, and the CO₂ dissolves preferentially — leaving a gas stream enriched to ≥97% CH₄. No solvents. No membranes. No chemical regeneration.

Raw Biogas1 bar · 50% CH₄
K-101 Feed Compressor1 → 8 bar(g)
T-101 PWS AbsorberCO₂ stripped
V-104 Dryer−20°C dew point
K-102 CBM Compressor8 → 200 bar(g)
V-103 Cylinders≥97% CH₄

Closed-Loop Water Regeneration

The scrubbing water is continuously regenerated in a closed-loop system — no liquid waste is discharged to the environment.

  1. V-105 Flash depressurization — water drops from 8 bar to 0.5 bar, releasing ~70% of dissolved CO₂ by Henry's Law.
  2. T-102 Atmospheric air stripping — countercurrent air removes residual dissolved CO₂ and trace H₂S.
  3. V-106 Caustic scrubber — neutralizes H₂S from stripper off-gas before atmospheric discharge.
  4. E-102 Plate-and-frame cooler — chills regenerated water to <20°C before recirculation to T-101.

Equipment Datasheet

TagServiceKey SpecificationStandard
D-101Anaerobic biodigester (CSTR)Commercial 100–200 m³ · 25–30 d HRT · mesophilic
K-101Feed gas compressor2-stage oil-free recip. · 15 kW · 1→8 bar(g)ASME B19.3
T-101PWS absorption columnDN250 × 9.0 m · 5.0 m PP Pall rings · SS316LASME VIII Div.1
V-104Twin-tower desiccant dryer4Å mol. sieve · −20°C dew point · 8-h auto cycle
K-102CBM compressor4-stage oil-free · 18.5 kW · 8→200 bar(g) · 50 Nm³/hASME B19.3
V-103CBM cylinder filling manifold50-L Type-I steel · 200 bar · CNG thread (ISO 11439)ISO 11439 / DOT-NGV
V-105Flash depressurization tankDN600 × 2200 mm · 0.5 bar(g)ASME VIII Div.1
T-102Atmospheric air stripperDN300 × 4500 mm · 2.0 m PP Pall rings
V-106Caustic scrubber (H₂S abatement)DN250 × 2000 mm · 10% NaOH
P-101 A/BProcess water pumps (duty/standby)15 m³/h · 90 m head · 7.5 kW each · SS316LISO 5199
E-102Process water cooler (PHE)50 kW duty · <20°C outlet · SS316L plates
XV-102H₂S bypass needle valveCalibrated raw-biogas blend · ~50 ppm H₂S target

⚠️ Methane Slip Disclosure

PWS systems typically exhibit 1.5–2.5% methane slip — this is a well-characterized physical limitation of the technology, not a design flaw. Membrane upgrading can achieve lower slip (0.3–0.7%), but at higher CAPEX, greater sensitivity to H₂S, and membrane replacement costs. DM-XTech selected PWS for its robustness, zero chemical consumption, and 60+ years of commercial reference. The 2% slip is accounted for in the mass balance and carbon-credit calculations; residual CH₄ in the stripper off-gas is monitored but not recovered at Phase 1 scale.

⚠️ H₂S Odorant — Important Caveat

The product retains approximately 50 ppm H₂S via a calibrated bypass blend. While this provides a natural "rotten egg" odorant for leak detection, it is higher than the synthetic THT/mercaptan odorization used in LPG (~5–15 ppm equivalent). H₂S is corrosive, toxic at sustained exposure (OSHA TWA 10 ppm), and combusts to SO₂. The 50 ppm level is acceptable in the product stream but requires:

  • Leak-tight cylinder valves and regulators
  • Ventilated storage cages
  • Consumer education that the "rotten egg" smell is intentional and normal
  • Future Phase 2 evaluation of synthetic odorant replacement if regulatory thresholds tighten

Process Safety · By Design

The plant is engineered to fail safely at every stage. Every hazardous area is zone-classified per IECEx / PNS IEC 60079; every pressure vessel has independent pressure relief; every compressor has an emergency shutdown (ESD) tied to gas detection.

Top 8 Hazards · Engineered Mitigations

HazardConsequenceEngineered Mitigation
Over-pressure of T-101Vessel rupture, gas releaseDual-redundant PSVs at 9.5 bar(g); rupture disc at 10.5 bar; pressure transmitter on DCS trip
Biogas leak in digester areaFlammable cloud formationContinuous LEL monitoring; Ex-rated equipment; forced ventilation; ESD on 25% LEL
H₂S exposure to operatorsAsphyxiation / toxicityFixed + portable H₂S monitors; 10 ppm TWA alarm; SCBA for confined space entry
Compressor seal failure (K-102)High-pressure CBM releaseSeal gas monitoring; vibration trip (ISO 10816-3 Zone B); automatic isolation
Cylinder over-fillCylinder ruptureMass flow meter + pressure transmitter redundant fill control; 10% over-pressure rupture disc
Water contamination in productDownstream corrosion, low qualityV-104 twin-tower dryer; on-line dew point analyzer; ≥−20°C dew point spec
Power failure during operationLoss of ventilation, ESD systemsUPS on DCS and gas detection (30 min); fail-safe SDVs; emergency vent on depressurization
Digester overload (shock feeding)Foam-over, pH crash, production lossGradual feed ramp-up; pH + VFA monitoring; controlled feed pumps on DCS

Safety Standards Compliance

The plant is engineered to Philippine Nuclear Research Institute / DOE / DENR safety standards for industrial gas installations. Cylinder handling follows PNS Philippine National Standards harmonized with ISO 11439 / DOT-NGV. No element of the plant design depends on operator perfect vigilance — the engineered safeguards are layered and independent.

Mass & Energy Balance · Standard Hub

At steady-state operation (50 Nm³/h nameplate, 82% utilization):

StreamRateBasis
Fresh azolla input47.6 kg per Nm³ CBMDerived: 1/(0.10×0.75×0.250)÷0.98 PWS recovery
Dry matter (DM)10% of freshStandard azolla value
Volatile solids (VS)75% of DMStandard herbaceous biomass
Methane produced250 L CH₄/kg VS (base case)Conservative mesophilic yield
Raw biogas volume~2× methane volume (50% CH₄)Typical for fresh herbaceous substrate
CBM product (after PWS)98% CH₄ recovery2% CH₄ slip accounted
CBM mass0.717 kg/Nm³ at STPStandard biomethane density
LPG equivalent displaced0.797 kg LPG per Nm³ CBMBTU parity basis
Compression electricity~1.0 kWh/Nm³K-101 + K-102 combined
Make-up water~5% of circulationClosed-loop PWS system
Digestate (organic fertilizer)~90% of fresh weightN-rich liquid + solid fraction